Journal
ORGANIC LETTERS
Volume 18, Issue 13, Pages 3286-3289Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01580
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- NIH [GM-64451]
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The catalytic Suzuki-Miyaura cross-coupling with chiral gamma,gamma-disubstituted allylboronates in the presence of RuPhos ligand occurs with high regioselectivity and enantiospecificity, furnishing nonracemic compounds with quaternary centers. Mechanistic experiments suggest that the reaction occurs by transmetalation with allyl migration, followed by rapid reductive elimination.
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