Journal
ORGANIC LETTERS
Volume 18, Issue 8, Pages 1900-1903Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00675
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Funding
- Western Light Talents Training Program of Chinese Academy of Sciences
- National Natural Science Foundation of China [21272227, 21402185]
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A straightforward and facile method has been developed to prepare 1,1-disubstituted hydrazines via Lewis base promoted direct reductive hydrazination. Under the catalysis of hexamethylphosphoramide (HMPA) and N,N-dimethylacetamide (DMAc), respectively, various ketones and aldehydes could react with phenylhdrazines to prepare 1,1-disubstituted hydrazines with good to high yields.
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