Journal
ORGANIC LETTERS
Volume 18, Issue 8, Pages 1924-1927Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00738
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Funding
- National Natural Science Foundation of China [21272275, 81430092]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- Program for Changjiang Scholars and Innovative Research Team in University [IRT_15R63]
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Spirotrichilins A (1) and B (2), two novel limonoids with an unprecedented spiro[cyclopenta[b]furan2,1'-cyclopentan] ring system in A/B/C rings, were isolated from the fruits of trichilia connaroides. Their planar structures and absolute configurations were established based on 1D-, 2D-NMR data, electronic circular dichroism (ECD) exciton chirality method and time-dependent density functional theory (TDDFT)/ECD calculation. A benzilic acid-like rearrangement in ring A was proposed as the key step in the plausible biogenetic pathway of 1 and 2.
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