Journal
ORGANIC LETTERS
Volume 18, Issue 8, Pages 1796-1799Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00522
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Funding
- National Natural Science Foundation of China [21402244]
- Foundation for Author of National Excellent Doctoral Dissertation of P. R. China [201425]
- Start-up Funding from Sun Yat-Sen University
- One Thousand Youth Talents Plan
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Synthesis of 2-alkenylquinoline by reductive olefination of quinoline N-oxide under metal-free conditions is disclosed. Practically, the reaction could be performed with quinoline as starting material via a one-pot, two-step process. A possible mechanism is proposed that involves a sequential 1,3-dipolar cycloaddition and acid-assisted ring opening followed by a dehydration process.
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