4.6 Article

A Boron Dipyrromethene (BODIPY)-Based CuII-Bipyridine Complex for Highly Selective NO Detection

Journal

CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 44, Pages 15486-15490

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502191

Keywords

BODIPY; cells; fluorescence; NO detection; quimiodosimeter

Funding

  1. European FEDER [MAT2012-38429-C04-01, MAT2012-38429-C04-02]
  2. Generalitat Valenciana [PROMETEOII/2014/047)]

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A BODIPY-containing Cu-II-bipyridine complex for the simple selective fluorogenic detection of NO in air and in live cells is reported. The detection mechanism is based on NO-promoted Cu-II to Cu-I reduction, followed by demetallation of the complex, which results in the clearly enhanced emission of the boron dipyrromethene (BODIPY) unit.

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