4.8 Article

Temperature-Responsive Switch Constructed from an Anthracene-Functionalized Pillar[5]arene-Based Host-Guest System

Journal

ORGANIC LETTERS
Volume 18, Issue 5, Pages 1092-1095

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00097

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Funding

  1. National Natural Science Foundation of China [21572076, 21372092]
  2. Natural Science Foundation of Hubei Province [2013CFA112, 2014CFB246]
  3. Wuhan scientific and technological projects [2015020101010079]
  4. Self-determined research funds of CCNU from the colleges' basic research and operation of MOE [CCNU15KFY005]

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A monofunctionalized anthracene pillar[5]arene (MAP5) was designed and synthesized by a click reaction. MAPS was bound to an ionic liquid through host-guest interactions to modify a gold interface. The bonding and release of MAPS was readily and reversibly controlled by temperature regulation. The developed temperature-responsive switch at an interface can be used in memory storage, drug delivery, and sensing.

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