Journal
ORGANIC LETTERS
Volume 18, Issue 6, Pages 1282-1285Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00172
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Funding
- NSFC/China [21421004, 21190033, 21561162003, 21372072]
- Eastern Scholar Distinguished Professor Program
- Programme of Introducing Talents of Discipline to Universities [B16017]
- NCET [NCET-13-0798]
- Basic Research Program of the Shanghai Committee of Science and Technology [13M1400802]
- Fundamental Research Funds for the Central Universities
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On-surface Ullmann coupling reaction of aryl chlorides has been achieved on Cu(111), Ag(111), and Au(111), and the mechanism has been investigated on the single molecule level using scanning tunneling microscopy and density functional theory. The different reactivity of the aryl halides was utilized to design a stepwise on-surface synthesis, which affords a zigzag template and then converts to 2D porous networks.
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