Journal
ORGANIC LETTERS
Volume 19, Issue 1, Pages 262-265Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03558
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Funding
- DST-India [SB/S1/OC-10/2014]
- CSIR-India [02(205)/14/EMR-II]
- IISERB
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A unique site selectivity switch has been achieved in the ruthenium-catalyzed C-H arylation reaction of N-acetyl-1,2-dihydroisoquinolines. This metal-mediated switch is antipodal to the previous report on the palladium-mediated C-4 C-H arylation on the same substrate. Mechanistic details reveal interesting aspects of the reaction pathway, and kinetic studies bring out the; difference in the modes of C-H-activation adopted by the two catalytic systems.
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