Journal
ORGANIC LETTERS
Volume 18, Issue 8, Pages 1780-1783Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00498
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Funding
- National Natural Science Foundation of China [21502049, 51573040]
- Hunan Provincial Natural Science Foundation of China [13JJ5018, 14JJ7028]
- Planned Science and Technology Project of Hunan Province, China [2015WK3003]
- Hunan Provincial Innovation Foundation for Postgraduate [CX2015B076]
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A novel copper/silver cocatalyzed oxidative coupling of vinylarenes with ICH2CF3 or ICH2CHF2 through a radical process has been developed. The transformation provides an attractive approach to beta-CF3/CHF2-substituted ketones, with the advantages of easily available starting materials and operational simplicity.
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