Journal
ORGANIC LETTERS
Volume 19, Issue 1, Pages 134-137Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03428
Keywords
-
Categories
Funding
- Science & Engineering Research Board (SERB), India [SR/S1/IC-56/2012]
Ask authors/readers for more resources
Two novel beta-hexaalkylated porphycenes, i.e., 2,3,7,12,13,17- (HOT) and 2,3,6,12,13,16-hexaethylporphycenes (HIT) were introduced for the first time in porphycene chemistry. These were synthesized through McMurry coupling reactions of new isomeric unsymmetrically substituted triethylbipyrrole dialdehydes. The positional effects of alkyl groups could be manifested through significant alteration in structure of porphycene cores and, as a consequence their photophysical properties, not noticed in beta-octaethylporphycene. HOT displays significant fluorescence accompanied by reasonable singlet oxygen generation ability.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available