Journal
ORGANIC LETTERS
Volume 19, Issue 1, Pages 74-77Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03346
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Funding
- MEXT [26105727]
- Uehara Memorial Foundation
- Grants-in-Aid for Scientific Research [15H00874, 26410117, 16K05720, 16J06021] Funding Source: KAKEN
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The enantioselective oxidative ring-opening reaction of aziridines with alpha-nitroacetates has been developed. Good yields and enantioselectivity were observed for the reaction of various aziridines using a novel cinchona alkaloid amide/NiBr2 catalyst. Both enantiomers of products could be obtained by using pseudoenantiomeric chiral catalysts. This process offers an efficient route for the synthesis of alpha-aminoketones.
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