Journal
ORGANIC LETTERS
Volume 18, Issue 24, Pages 6276-6279Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b03073
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Funding
- International S&T Cooperation Program of China [2013DFR70580]
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A tandem catalytic strategy enabling one-pot, three-component couplings of electron-rich phenols, 2-nitro 1,3-enynes, and vinyl ketones was achieved. This chemistry combined mechanistically distinct [3 + 3]-annulation and nitro Michael addition using a single squaramide catalyst, leading to the construction of novel chiral quaternary 3-nitrochromane architecture with high chemo-, regio-, and stereoselectivity.
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