Journal
ORGANIC LETTERS
Volume 18, Issue 19, Pages 4856-4859Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02338
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Funding
- JSPS [JP 15K13696, JP 15H05485, JP 24225002]
- Grants-in-Aid for Scientific Research [15K13696, 15H05485] Funding Source: KAKEN
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A copper-catalyzed aminoboration of alkenyl dan boronates (dan = 1,8-diaminonaphthyl) with diboron reagents and hydroxylamines, has been developed. The reaction proceeds regio- and stereoselectively to form the corresponding beta-boryl-alpha-aminoboronic acid derivatives of potent interest in medicinal chemistry. Additionally, the ligand-controlled syn/anti diastereoselectivity switching and,preliminary asymmetric catalysis are also described.
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