Journal
ORGANIC LETTERS
Volume 18, Issue 2, Pages 328-331Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03518
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Funding
- National Key Basic Research Program of China [2012CB224802]
- NSF of China [21371107]
- Tsinghua-Peking Joint Centers for Life Sciences
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Herein we report a Rh(I)-catalyzed two carbon insertion into C-C bonds of benzocyclobutenols by employing symmetrical and unsymmetrical allenes. This reaction provides rapid access to alkylidene tetralins bearing two adjacent stereogenic centers in good yields and diasteroselectivities.
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