Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 19, Pages 7127-7134Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201500382
Keywords
allylic compounds; amination; asymmetric catalysis; iridium; supported catalysts
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The first immobilized catalyst for Ir-catalyzed asymmetric allylic aminations is described. The catalyst is a cationic (-allyl)Ir complex bound by cation exchange to an anionic silica gel support. Preparation of the catalyst is facile, and the supported catalyst displayed considerably enhanced activity compared with the parent homogeneous catalyst. Up to 43consecutive amination runs were possible in recycling experiments.
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