Journal
ORGANIC LETTERS
Volume 18, Issue 12, Pages 2832-2835Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01078
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Funding
- UGC
- CSIR-New Delhi [CSC-0108]
- Eli Lilly
- Jubilant-Bhartia Foundation
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A general approach involving the insertion of in situ: generated aryne into the C-C bond of cyclic 1,3-diketones for rapidly assembling functionalized benzo-fused medium ring carbocycles delineated. The efficacy of the methodology has been demonstrated through a concise total synthesis of pentacyclic natural product radermachol.
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