Journal
ORGANIC LETTERS
Volume 18, Issue 15, Pages 3762-3765Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01782
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Funding
- National Natural Science Foundation of China [21272085, 21472056]
- Fundamental Research Funds for Central Universities [CCNU15ZX002]
- Central China Normal University [2015YBYB065]
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A transition-metal-free coupling annulation reaction of arynes, ketones, and alkynoates has been demonstrated: Using this formal [2 + 2 + 2] cycloaddition reaction, a wide variety of naphthalene derivatives were conveniently constructed in one pot with high efficiency. In addition, this novel and valid annulation has been successfully applied to the synthesis of 1-phenanthrenol derivatives.
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