Journal
ORGANIC LETTERS
Volume 18, Issue 21, Pages 5712-5715Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b02941
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Funding
- National Basic Research Program of China [2013CB910700]
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Pyrrolo[1,2-a]indole is a common structural motif found in many natural products and pharmaceuticals. A silver-mediated oxidative phosphinoylation of N-propargyl-substituted indoles was used to construct a variety of 2-phosphinoyl-9H-pyrrolo[1,2-a]indoles under mild conditions. This transformation offers a straightforward route to the formation of the CP bond, cyclization, and isomerization in one step.
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