4.8 Article

Selective H/D Exchange at Vinyl and Methylidene Groups with D2O Catalyzed by an Iridium Complex

Journal

ORGANIC LETTERS
Volume 18, Issue 15, Pages 3674-3677

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01721

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Funding

  1. JSPS KAKENHI Grant [JP15H03810]
  2. Grants-in-Aid for Scientific Research [15H03810] Funding Source: KAKEN

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Selective H/D exchange at vinyl and methyl,, idene groups of alkenes with D2O was promoted by an iridium catalyst generated in situ from a hydroxoiridium complex and N-mesylbenzamide.

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