Journal
ORGANIC LETTERS
Volume 18, Issue 10, Pages 2471-2474Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b01042
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Funding
- National Basic Research Program of China [2015CB931900, 2012CBA01200]
- National Natural Science Foundation [21421002, 21472222, 21502214]
- Chinese Academy of Sciences [XDA02020105, XDA02020106]
- Syngenta
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The trifluoromethylcarbene (:CHCF3) was found to be conveniently generated from (2,2,2-trifluoroethyl)diphenyl-sulfonium triflate (Ph2S+CH2CF3 -OTf, which was successfully applied in Fe-catalyzed cyclopropanation of olefins, giving the corresponding trifluoromethylated cyclopropanes in high yields.
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