Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 18, Pages 6673-6677Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201406554
Keywords
asymmetric synthesis; biaryl compounds; cross-coupling; ligand design; phosphanes
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Funding
- NSFC [21272100, 21472076]
- Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT1138]
- Program for New Century Excellent Talents in University [NCET-11-0215, lzujbky-2013-k07]
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Efficient asymmetric Suzuki-Miyaura coupling reactions have been employed for the first time to synthesize chiral biaryl compounds with phosphinate groups as chiral auxiliaries. A series of functionalized chiral biaryls are thereby synthesized in excellent yields and good diastereoselectivities (up to > 95: 5 d.r.) and axially chiral monophosphorus ligands are obtained through further functionalizations.
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