Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 44, Pages 10352-10356Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob02090a
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Funding
- Naito Foundation
- Asahi Glass Foundation
- JSPS [15K07852]
- Grants-in-Aid for Scientific Research [15K07852] Funding Source: KAKEN
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Barluenga's reagent (IPy2BF4, Py = pyridine) treated with HBF4 efficiently catalyzes the inter- and intramolecular alkyne-carbonyl metathesis of unactivated alkynes with aldehydes or ketones, most of which proceed at room temperature. This work represents the first catalytic application of the Barluenga's reagent.
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