4.6 Review

Enantioselective oxidative boron Heck reactions

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 24, Pages 5357-5366

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01984b

Keywords

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Funding

  1. Leverhulme Trust [F/00 276/O]
  2. EPSRC [EP/K00736X/1]
  3. Engineering and Physical Sciences Research Council [EP/K00736X/1] Funding Source: researchfish

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This review highlights the use of the oxidative boron Heck reaction in enantioselective Heck-type couplings. The enantioselective oxidative boron Heck reaction overcomes several limitations of the traditional Pd(0)-catalysed Heck coupling and has subsequently allowed for intermolecular couplings of challenging systems such as cyclic enones, acyclic alkenes, and even site selectively on remote alkenes.

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