Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 5, Pages 1536-1539Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob02551f
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Funding
- Ministry of Sciences and Technology of China [2012ZX09502-002]
- Natural Science Foundation of China [21432012, 21372253]
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Stereoselective beta-rhamnopyranosylation remains a challenge, due to the unfavorable anomeric effect and steric hindrance of the C2-substituent; herein, this challenge is addressed with a gold(I)-catalyzed S(N)2-like glycosylation protocol employing alpha-rhamnopyranosyl 2-alkynyl-4-nitro-benzoates as donors.
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