Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 26, Pages 6201-6204Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00942e
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Funding
- National Natural Science Foundation of China [21472163]
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A Rh(III)-catalyzed C-H activation/cyclization of oximes and alkenes for facile and regioselective access to isoquinolines has been developed. This protocol features mild reaction conditions and easily accessible starting materials, and has been applied to the concise synthesis of moxaverine. A kinetic isotope effect study was conducted and a plausible mechanism was proposed.
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