Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 40, Pages 13894-13899Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201501672
Keywords
catalysis; C-H bond oxidation; multidimensional networks; metal-organic frameworks; SCSC transformations
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Funding
- 973 Program [2013CB834704]
- Provincial Key Project of China [7131253]
- National Natural Science Foundation of China [21471018, 21404010, 21201018, 21401094]
- 1000 Plan (Youth)
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Metal-organic frameworks (MOFs), as a class of microporous materials with well-defined channels and rich functionalities, hold great promise for various applications. Yet the formation and crystallization processes of various MOFs with distinct topology, connectivity, and properties remain largely unclear, and the control of such processes is rather challenging. Starting from a 0D Cu coordination polyhedron, MOP-1, we successfully unfolded it to give a new 1D-MOF by a single-crystal-to-single-crystal (SCSC) transformation process at room temperature as confirmed by SXRD. We also monitored the continuous transformation states by FTIR and PXRD. Cu MOFs with 2D and 3D networks were also obtained from this 1D-MOF by SCSC transformations. Furthermore, Cu MOFs with 0D, 1D, and 3D networks, MOP-1, 1D-MOF, and HKUST-1, show unique performances in the kinetics of the C-H bond catalytic oxidation reaction.
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