Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 14, Issue 24, Pages 5843-5860Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ob00861e
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Funding
- CSIR, New Delhi
- IIT Kanpur
- DST, New Delhi [SB/S1/OC-01/2014]
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Cu(OTf)(2) catalyzed [6 + 2] cycloaddition reaction of indolyl-2-carbinols with various dienophiles such as indole derived alpha,beta-unsaturated esters, ketones, nitriles and cinnamates is described. The strategy was further applied for the synthesis of optically active pyrrolo[1,2-a]indoles in >97% de using the chiral auxiliary based approach.
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