S, Pb, and Sr isotope geochemistry and genesis of Pb-Zn mineralization in the Huangshaping polymetallic ore deposit of southern Hunan Province, China

The Huangshaping Pb-Zn-W-Mo polymetallic deposit, located in southern Hunan Province, China, is one of the largest deposits in the region and is unique for its metals combination of Pb-Zn-W-Mo and the occurrence of significant reserves of all these metals. The deposit contains disseminated scheelite and molybdenite within a skarn zone located between Jurassic granitoids and Carboniferous sedimentary carbonate, and sulfide ores located within distal carbonate-hosted stratiform orebodies. The metals and fluids that formed the W-Mo mineralization were derived from granitoids, as indicated by their close spatial and temporal relationships. However, the source of the Pb-Zn mineralization in this deposit remains controversial. Here, we present new sulfur, lead, and strontium isotope data of sulfide minerals (pyrrhotite, sphalerite, galena, and pyrite) from the Pb-Zn mineralization within the deposit, and these data are compared with those of granitoids and sedimentary carbonate in the Huangshaping deposit, thereby providing insights into the genesis of the Pb-Zn mineralization. These data indicate that the sulfide ores from deep levels in the Huangshaping deposit have lower and more consistent delta S-34 values (-96 m level: + 4.4 parts per thousand to + 6.6 parts per thousand, n = 13) than sulfides within the shallow part of the deposit (20 m level: +8.3 parts per thousand to +16.3 parts per thousand, n = 19). The delta S-34 values of deep sulfides are compositionally similar to those of magmatic sulfur within southern Hunan Province, whereas the shallower sulfides most likely contain reduced sulfur derived from evaporite sediments. The sulfide ores in the Huangshaping deposit have initial Sr-87/Sr-86 ratios (0.707662-0.709846) that lie between the values of granitoids (0.709654-0.718271) and sedimentary carbonate (0.707484-0.708034) in the Huangshaping deposit, but the ratios decreased with time, indicating that the ore-forming fluids were a combination of magmatic and formation-derived fluids, with the influence of the latter increasing over time. The lead isotopic compositions of sulfide ores do not correlate with sulfide type and define a linear trend in a Pb-207/Pb-204 vs. Pb-206/Pb-204 diagram that is distinct from the composition of the disseminated pyrite within sedimentary carbonates and granitoids in the Huangshaping deposit, but is similar to the lead isotopic composition of sulfides within coeval skarn Pb-Zn deposits in southern Hunan Province. In addition, the sulfide ores have old signatures with relative high Pb-207/Pb-206 ratios, suggesting that the underlying Paleoproterozoic basement within southern Hunan Province may be the source of metals within the Huangshaping deposit. The isotope geochemistry of sulfide ores in the Huangshaping deposit shows a remarkable mixed source of sulfur and ore-forming fluids, and the metals were derived from the basement. These features are not found in representative skarn-type Pb-Zn mineralization located elsewhere. The ore-forming elements (S, Pb, and Zn) from the granitoids made an insignificant contribution to sulfide precipitation in this deposit. However, the emplacement of granitoids did provide large amounts of heat and fluids to the hydrothermal system in this area and extracted metals from the basement rocks, indicating that the Jurassic magmatism associated with the Huangshaping deposit was crucial to the Pb-Zn mineralization. (C) 2016 Elsevier B.V. All rights reserved.