Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 43, Pages 15439-15445Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502421
Keywords
hydrogen; mesoporous materials; nanoparticles; self-assembly; supported catalysts
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Funding
- National Outstanding Youth Science Foundation of China [51125003]
- National Natural Science Foundation of China [51471168]
- 985 Project of South China University of Technology
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The development of active, selective, and robust catalysts is a key issue in promoting the practical application of hydrazine monohydrate (N2H4H2O) as a viable hydrogen carrier. Herein, the synthesis of a supported Ni-Pt bimetallic nanocatalyst on mesoporous ceria by a one-pot evaporation-induced self-assembly method is reported. The catalyst exhibits exceptionally high catalytic activity, 100% selectivity, and satisfactory stability in promoting H-2 generation from an alkaline solution of N2H4H2O at moderate temperatures. For example, the Ni60Pt40/CeO2 catalyst enabled complete decomposition of N2H4H2O to generate H-2 at a rate of 293h(-1) at 30 degrees C in the presence of 2M NaOH, which compares favorably with the reported N2H4H2O decomposition catalysts. Phase/structural analysis by XRD, TEM, and Auger electron spectroscopy was conducted to gain insight into the excellent catalytic performance of the Ni-Pt/CeO2 catalyst.
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