Journal
CHEMISTRY-A EUROPEAN JOURNAL
Volume 21, Issue 40, Pages 13961-13970Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201502385
Keywords
1,3-azaborinine; B,N-heterocycles; imidazoindoles; photolysis; thermal isomerization
Categories
Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- NSERC
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NHC-B, N-heterocyclic compounds have been found to act as convenient precursors for obtaining either 1,3-azaborinine or 1H-imidazo[1,2-a]indole derivatives, which are two different and rare classes of compounds. The formation of these two classes of compounds from the NHC-B, N-heterocycles is highly selective depending on the external stimuli employed, and the resulting products have been studied for their interesting chemical and photophysical properties. The mechanism and possible reaction pathways of the unusual transformation are established by computational studies.
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