Journal
CHEMISTRY OF MATERIALS
Volume 27, Issue 21, Pages 7388-7394Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.5b03114
Keywords
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Funding
- National Science Foundation (NSF) [DMR-0905231, DMR-1206409, DMR-1310258]
- Department of Chemistry at Virginia Tech.
- Office of Science, Office of Basic Energy Sciences, Scientific User Facilities Division of the U.S. Department of Energy [DE-AC02-05CH11231]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1206409] Funding Source: National Science Foundation
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A two-step synthetic strategy has been developed to achieve functionalized nanoporous polymers via the deprotection of the cross-linked polymer precursors containing tert-butyl carboxylate-functionalized stilbene or styrene and N-phenylmaleimide alternating sequences. Three different deprotection methods to generate nanoporosity were examined in this work. The resulting nanoporous polymers showed a significant increase in BET surface area. The effects of cross-linking density and the stiffness of the alternating sequences on the nanoporosity of these polymers were studied. The resulting nanoporous polymers were also investigated as potential CO2 sorbents.
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