4.1 Article

Synthesis of 1-(N-nitropyrazolyl)-1De-tetrazoles - a new type of heteronuclear N-nitropyrazole derivatives

Journal

CHEMISTRY OF HETEROCYCLIC COMPOUNDS
Volume 51, Issue 8, Pages 695-703

Publisher

SPRINGER
DOI: 10.1007/s10593-015-1760-z

Keywords

NO donors; N-nitropyrazoles; pyrazoles; tetrazoles; multinuclear NMR; N-nitration; X-ray structural study

Funding

  1. Russian Science Fund [RNF 14-50-00126]

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A general method has been developed for the synthesis of 1-pyrazolyl-1De-tetrazoles, and N-nitration of these compounds was studied. The structural features affecting the direction of nitration were identified. A series of 1-(N-nitropyrazolyl)-1De-tetrazoles was obtained, representing a new type of heteronuclear N-nitropyrazole derivatives.

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