Journal
CHEMISTRY LETTERS
Volume 44, Issue 6, Pages 779-781Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.150154
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Funding
- ERATO program from JST
- JSPS
- World Premier International Research Center (WPI) Initiative, Japan
- Grants-in-Aid for Scientific Research [13F03035] Funding Source: KAKEN
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The first nickel-catalyzed aromatic C-H borylation is described. In the presence of catalytic amounts of [Ni(cod)(2)], tricyclopentylphosphine, and CsF, benzene and indole derivatives can be borylated with B(2)pin(2). The N-heterocyclic carbene IPr was also found to be an effective ligand. Kinetic isotope effect experiments showed that C-H cleavage is likely involved in the rate-determining step.
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