Journal
CHEMISTRY LETTERS
Volume 44, Issue 9, Pages 1185-1187Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.150328
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Funding
- Regional Innovation Cluster Program (Global type), Yamaguchi Green Materials Cluster, from the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- Grants-in-Aid for Scientific Research [15K04613] Funding Source: KAKEN
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Although the polymer complex, poly(nickel 1,1,2,2-ethenetetrathiolate) (Ni-PETT), is an interesting n-type organic thermoelectric material, it is insoluble in all kinds of solvents. We prepared nanoparticles of Ni-PETT (n-Ni-PETTs) using a surfactant, dodecyltrimethylammonium bromide, as an additive during the synthesis of the polymer complex. The n-Ni-PETTs were well dispersed in an organic solvent like N-methyl-2-pyrrolidone, and could provide smooth, tough, and flexible n-type thermoelectric films by hybridization with poly(vinyl chloride).
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