Journal
CHEMISTRY LETTERS
Volume 44, Issue 11, Pages 1610-1612Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.150688
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Funding
- JSPS KAKENHI MEXT Project of Integrated Research on Chemical Synthesis from Ministry of Education, Culture, Sports, Science and Technology, Japan, the Molecular Systems Research project of RIKEN Advanced Science Institute [24109013, 24550048, 2662028, 15H05477]
- [252926]
- Grants-in-Aid for Scientific Research [26620028, 25288021, 15H05477, 13J02926, 24109013] Funding Source: KAKEN
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Treatment of a stable dialumane derivative with an excess of t-butyl isocyanide resulted in the homocoupling of the isocyanide to form a diaminoalkyne skeleton. A one-to-one insertion product of the isocyanide with the dialumane should be the intermediate for the generation of the diaminoalkyne derivative.
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