Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 18, Pages 4023-4030Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500500
Keywords
arylmethanes; fluorinated alcohols; indoles; 3-indolylmethanol; S(N)1-type reaction
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Funding
- National Natural Science Foundation of China [21102142, 41322037, 41130858]
- Program of Natural Science Foundation of Shandong Province of China [JQ201510]
- Talents of High Level Scientific Research Foundation of Qingdao Agricultural University [6631112323, 6631115015]
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This paper describes an efficient S(N)1-type reaction of 3-indolylmethanols with miscellaneous nucleophiles, featuring a catalyst-free procedure, low cost, wide substrate scope and mild reaction conditions. This approach provides green and efficient methods for the synthesis of diverse 3-substituted indolyl derivatives as well as unsymmetrical bisindolylmethanes and triarylmethanes.
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