Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 4, Pages 739-746Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400925
Keywords
aerobic oxidation; alcohols; copper; flow chemistry; 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO)
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Aerobic oxidation using a combination of copper salts and 2,2,6,6-tetramethylpiperidine N-oxyl (TEMPO) represent useful tools for organic synthesis and several closely related catalyst systems have been reported. To gain further insights, these catalytic systems were evaluated in a gas-liquid segmented flow device. The improvement of oxygen mass transfer has a significant influence on the turnover-limiting step. Hence, an improved catalytic system using copper(II) as copper source was implemented in a microreactor for the safe and efficient oxidation of primary alcohol.
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