4.7 Article

Visible Light-Mediated Metal-Free Synthesis of Vinyl Sulfones from Aryl Sulfinates

Journal

ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 9, Pages 2050-2054

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500142

Keywords

aryl sulfinates; metal-free conditions; photocatalysis; vinyl sulfones; visible light

Funding

  1. German Science Foundation (DFG) [GRK 1626]

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Visible light and eosin Y catalyze the synthesis of vinyl sulfones from aryl sulfinates and alkenes by a photoredox process. The reaction scope is broad in aryl sulfinates and alkenes and the general and simple procedure provides a metal-free alternative for the synthesis of synthetically valuable vinyl sulfones.

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