Nitrogen-doped carbon dots as a fluorescence probe suitable for sensing Fe3+ under acidic conditions

To obtain nitrogen-doped carbon dots (N-CDs) for sensing Fe3+ under acidic conditions, robust and highly fluorescent N-CDs were prepared by one-pot hydrothermal treatment of dopamine and ethylenediamine. The N-CDs have a relatively uniform size of approximately 4.9 nm and good water dispersibility. The N-CDs exhibit strong visible fluorescence (ca. 497 nm) and high stability at low pH (i.e. 2-3). The FTIR spectra and the XPS analyses indicated that primary amines and distinctive catechol groups exist on the surface of the N-CDs. The FTIR spectra further prove that the catechol groups on their surfaces can be oxidized to the quinone species by Fe3+, contributing to fluorescence response to Fe3+. Thus, the N-CDs as fluorescence probes allowed the detection of Fe3+ under acidic conditions, which has been verified in this work.