4.6 Article

Non-mercury catalytic acetylene hydrochlorination over a NH4F-urea-modified Pd/HY catalyst for vinyl chloride monomer production

Journal

NEW JOURNAL OF CHEMISTRY
Volume 40, Issue 4, Pages 3019-3023

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj03338a

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Funding

  1. National Natural Science Foundation of China [21263025, U1403293]
  2. Graduate Research and Innovation Program of Xinjiang [XJGRI2014023]

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A Pd/HY zeolite catalyst modified with ammonium fluoride and urea (Pd/NH4F-urea-HY) was efficiently applied in an acetylene hydrochlorination reaction. It exhibited an enhanced catalytic performance compared to the untreated Pd/HY catalyst, which was attributed to the presence of ammonium fluoride and urea partly inhibiting carbon deposition and Pd2+ reduction.

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