Journal
NEW JOURNAL OF CHEMISTRY
Volume 40, Issue 3, Pages 2592-2600Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5nj02875b
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Funding
- MOST [2014AA032802]
- national sci-tech support plan
- National Natural Science Foundation of China (NSFC) [51372264]
- Science and Technology Commission of Shanghai Municipality (STCSM) [13NM1402200]
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Hierarchical VO2(M)-ZnO dandelions with ZnO nanorods grown radially on VO2(M) nanoparticle cores have been successfully fabricated for the first time. In these dandelions, the VO2(M) NPs were prepared by a TiO2 seed-assisted hydrothermal method and the dandelion-like ZnO nanorods were formed over two steps: heteroseed-induced nucleation and the subsequent heteroepitaxial growth processes. The coupled ZnO could increase the chemical stability of VO2(M) at relatively high temperatures. In addition, the VO2(M)-ZnO composite film with decreased phase transition temperature (T-c = 62.6 degrees C) simultaneously displayed an enhanced visible transmission (Tvis-l = 52.2%) and solar modulating ability (Delta T-sol = 9.3%) as compared with the pure VO2(M) film. Besides, the VO2(M)-ZnO dandelions also exhibited improved photocatalytic performance, likely due to the synergistic effect of the VO2(M)-ZnO heterojunction, unique dandelion-like hierarchical structure and high specific surface area. This is the first report of such a single VO2(M)-ZnO dandelions structure with energy saving and environmental protection effects that offer significant potential for creating a multifunctional smart coating.
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