Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 5, Pages 907-911Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500030
Keywords
aryl chlorides; C-N bond formation; N-heterocyclic carbenes; nickel catalysts
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Funding
- MINECO [CTQ2011-24502, CTQ2ss14-52769-C3-3-R]
- Junta de Andalucia [P07-FQM-02745]
- Consolider Ingenio [CSD2006-003]
- Ministerio de Economia y Competitividad
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A new and efficient nickel-based protocol for the N-arylation of indoles and carbazoles with aromatic chlorides, the least expensive of the aryl halides, is described. The procedure provides selectively N-(hetero)arylation products in good to high yields, in short reaction times and without adding an excess of ligands.
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