3.9 Article

Titanium Dioxide Thin Films Deposited by Electric Field-Assisted CVD: Effect on Antimicrobial and Photocatalytic Properties

Journal

CHEMICAL VAPOR DEPOSITION
Volume 21, Issue 1-3, Pages 63-70

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/cvde.201407145

Keywords

Catalytic properties; Semiconductors; Surface properties; Thin films; Vapor deposition

Funding

  1. National Funds from FCT - Fundacao para a Ciencia e a Tecnologia [PEst-OE/EQB/LA0016/2013]
  2. Fundacao para a Ciencia e a Tecnologia [SFRH/BPD/86483/2012]
  3. Fundação para a Ciência e a Tecnologia [SFRH/BPD/86483/2012] Funding Source: FCT

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Thin films of anatase titanium dioxide are deposited on fluorine-doped tin oxide (FTO) glass substrates utilizing the electric field-assisted aerosol (EA) CVD reaction of titanium isopropoxide in toluene at 450 degrees C. The as-deposited films are characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy (RS), and UV-vis spectroscopy. The photoactivity and antibacterial activity of the films are also assessed. The characterization analysis reveals that the use of an electric field affects the film microstructure, its preferential orientation, and the functional properties. XRD of the anatase films reveals that the application of electric fields causes a change in the preferential orientation of the films from (101) to (004) or (211) planes, depending on the strength of the applied field during the deposition.

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