Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 2-3, Pages 366-370Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201400798
Keywords
C-C coupling; C-H activation; iodobenzene; N-phenylpivalamide; rhodium; homogeneous catalysis
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Funding
- Ministry of Science and Technology of the Republic of China [NSC 102-2628-M-007-005, NSC 102-2633-M-007-002]
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An efficient o-arylation of pivalamides by aryl iodides via rhodium(III)-catalyzed C-H activation is demonstrated for the first time. Further, the biaryl products can be converted effectively into biologically active phenanthridine and phenanthridinone derivative.
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