Journal
MOLBANK
Volume 2023, Issue 3, Pages -Publisher
MDPI
DOI: 10.3390/M1699
Keywords
X-ray structure; structural revision; hydrogen bonding; 1,3-dioxolan-4-one
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X-ray diffraction analysis confirmed that the product formed by base-induced dimerization matches the described compound structure, rather than the previously proposed isomeric structure. Additionally, a similar compound derived from a different substrate was obtained and characterized.
The product formed by base-induced dimerisation of (2S,5S)-2-tert-butyl-5-methyl-1,3-dioxolan-4-one is shown by X-ray diffraction to be the title compound and not the isomeric fused-ring 1,3-dioxolane/1,3-dioxane-4-one structure proposed by previous researchers. The analogous compound derived from (2S,5S)-5-benzyl-2-tert-butyl-1,3-dioxolan-4-one has also been obtained and characterised.
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