Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 18, Pages 3863-3867Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500816
Keywords
asymmetric reactions; diaminomethylenemalononitrile; hydrophosphonylation; organocatalysts; Pudovik reaction
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Funding
- Grants-in-Aid for Scientific Research [15K18838] Funding Source: KAKEN
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For the asymmetric hydrophosphonylation of aldehydes, an efficient organocatalytic approach with a diaminomethylenemalononitrilebased hydrogen-bonding donor catalyst is presented. The catalyst induces high yields and excellent enantioselectivities (up to 98% yield, 96% ee).
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