3.8 Article

The evolution of coil-less inductive behaviour in La-doped Sr2MnO4

Journal

EMERGENT MATERIALS
Volume -, Issue -, Pages -

Publisher

SPRINGERNATURE
DOI: 10.1007/s42247-023-00562-4

Keywords

Negative permittivity; Layered perovskite; La substituted Sr2MnO4; Coil-less inductor; Drude Lorentz model

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The powder and ceramics of La-substituted layered oxides LaxSr2-xMn1-xO4 were synthesised using solid-state reaction technique. The synthesized compositions exhibited coil-less inductive characteristics, indicating their potential as coil-less inductors.
The powder and ceramics of La-substituted layered oxides LaxSr2-xMn1-xO4 (x = 0.3, 0.5, 0.7) were synthesised using the solid-state reaction technique. All synthesised compositions have tetragonal structures with space groups I4/mm that are identical to Sr2MnO4, as shown by the Rietveld refinement. XPS spectroscopy demonstrated that Mn exists in the mixed-valence forms Mn3+& Mn4+. Studies of the relationship between AC conductivity and permittivity in response to temperature (30-300(degrees)C) and frequency (1 kHz-2 MHz) have demonstrated the existence of negative permittivity over the whole test range. The observed negative permittivity is a result of free carriers oscillating plasmonically between 1 kHz and 2 MHz as a consequence of thermal excitation processes. The modelling of impedance data using various combinations of resistors and inductors exhibited the coil-less inductive characteristics of the samples. The inductive nature of samples indicates the possibility of designing synthesised compositions as coil-less inductors.

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