Journal
CHEMICAL RECORD
Volume 16, Issue 1, Pages 141-158Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201500220
Keywords
asymmetric synthesis; hydrophosphination; metallacycles; P ligands; palladium
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Funding
- Nanyang Technological University
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Our journey in organophosphorus research over the past 26 years is compiled in this Personal Account. Advances in palladacycle design have engendered a shift in our focus from template-mediated transformations to catalysis for the direct preparation of chiral phosphines containing a wide variety of functional groups. Novel approaches to access previously inaccessible phosphines and their applications in cancer research are summarized herein.
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