Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 10, Pages 2229-2232Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201401078
Keywords
amides; C-H activation; density functional calculations; ruthenium; silanes
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The ruthenium-catalyzed dehydrogenative silylation of benzamides with 1,1,1,3,5,5,5-heptamethyltrisiloxane took place at ortho-positions of the benzene ring. Several benzamides containing both electron-donating and electron-withdrawing groups could be used in this silylation. Density functional theory (DFT) calculations and kinetic isotope effect experiments suggest that the catalytic cycle should involve the C-Si bond formation as rate-determining step.
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