Journal
CHEMICAL RECORD
Volume 15, Issue 5, Pages 907-924Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/tcr.201500203
Keywords
asymmetric synthesis; homogeneous catalysis; hydrogen transfer; imines; organocatalysis
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Funding
- Ministerio de Ciencia e Innovacion (MICINN) [CTQ2007-62771/BQU, CTQ2010-20387]
- CONSOLIDER INGENIO [2010-CDS2007-00006, CTQ2011-24151, CTQ2011-24165]
- Ministerio de Economia y Competitividad (MINECO) [CTQ2013-43446-P, CTQ2014-51912-REDC, CTQ2014-53695-P]
- FEDER
- Generalitat Valenciana [PROMETEO 2009/039, PROMETEOII/2014/017]
- University of Alicante
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In this review article recent developments in the asymmetric transfer hydrogenation of imines from 2008 up to today are presented. The main methodology involves either metal-catalyzed procedures in the presence of a chiral ligand or organocatalyzed technologies using a Hantzsch ester and a chiral BINOL-derived phosphoric acid. The most important procedures are collected, paying special attention to the application of this methodology in synthetic organic chemistry.
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